项目名称: 基于纳米催化发光动力学的多维光谱传感器研究
项目编号: No.21675113
项目类型: 面上项目
立项/批准年度: 2017
项目学科: 数理科学和化学
项目作者: 张立春
作者单位: 四川大学
项目金额: 30万元
中文摘要: 气体传感器在检测有毒有害气体方面具有重要作用,在关系国计民生的众多领域都有广泛的应用。发展基于单个传感元件、测定同一类信号参数就能实现多种物质快速识别的传感方法是传感器发展的一个重要方向,具有重要的现实意义。催化发光是物质在固体催化剂表面发生催化反应时伴随的化学发光现象,作为一种很有发展前景的传感原理被引入气体传感器件的研制。因催化发光包含扩散、吸附、反应速率、发光中间体等多层面的动力学过程,产生的发光光谱含有多个维度(波长、光强、峰位、峰形、寿命等)的特征信息。本申请拟在可控合成开发筛选高效纳米催化剂基础上,深入研究催化发光反应的动力学特性,进一步挖掘其光谱富含的多维信息,结合适当的模式算法,发展新的基于单个传感单元、只需测定催化发光光谱就能实现多种物质快速识别的多维光谱传感器,并将之用于环境VOCs的检测;从而拓展催化发光传感器的应用范围,为实际气态组分的传感分析提供更多方法。
中文关键词: 纳米材料;调控合成;催化发光;分子识别;气体传感器
英文摘要: Gas sensors play an important role in detection of poisonous and harmful gases, and have been extensively applied in many fields related with national economy and people’s livelihood. In terms of practical application, to develop new identification method based on a single sensing unit and detection of the same kind of signals for facile discrimination many compounds from each other is an important direction of development of sensors. Cataluminescence (CTL) emitted on the surface of solid materials during a catalytic reaction is a very interesting phenomenon, and has been considered as a promising transduction principle for gas sensor. The CTL is a multi-step kinetic process, including diffusion, adsorption and desorption, reaction rate, luminescent intermediates, etc. So the obtained CTL spectra contain multidimensional characteristic information (wavelength, intensity, peak position, peak shape, life, etc.) for helpful discrimination of various compounds. On the basis of controllable synthesis of highly efficient nano catalysts, this application aims to develop a new molecular identification method through deeply studying the CTL kinetic process and multidimensional characteristic spectra. This method would use a single CTL sensing unit only to detect the CTL signals and adopts appropriate algorithm. The new molecular identification method could be used to discriminate and identify volatile organic compounds (VOCs), which are expected to expand CTL’s use and to provide more effective methods for the gaseous components recognition and analysis.
英文关键词: nanomaterial;controllable synthesis;cataluminescence;molecular recognication;gas sensor