Digital technologies have dramatically accelerated the digital transformation in process industries, boosted new industrial applications, upgraded the production system, and enhanced operational efficiency. In contrast, the challenges and gaps between human and artificial intelligence (AI) have become more and more prominent, whereas the digital divide in process safety is aggregating. The study attempts to address the following questions: (i)What is AI in the process safety context? (ii)What is the difference between AI and humans in process safety? (iii)How do AI and humans collaborate in process safety? (iv)What are the challenges and gaps in human-AI collaboration? (v)How to quantify the risk of human-AI collaboration in process safety? Qualitative risk analysis based on brainstorming and literature review, and quantitative risk analysis based on layer of protection analysis (LOPA) and Bayesian network (BN), were applied to explore and model. The importance of human reliability should be stressed in the digital age, not usually to increase the reliability of AI, and human-centered AI design in process safety needs to be propagated.

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