We study the spectral properties of flipped Toeplitz matrices of the form $H_n(f)=Y_nT_n(f)$, where $T_n(f)$ is the $n\times n$ Toeplitz matrix generated by the function $f$ and $Y_n$ is the $n\times n$ exchange (or flip) matrix having $1$ on the main anti-diagonal and $0$ elsewhere. In particular, under suitable assumptions on $f$, we establish an alternating sign relationship between the eigenvalues of $H_n(f)$, the eigenvalues of $T_n(f)$, and the quasi-uniform samples of $f$. Moreover, after fine-tuning a few known theorems on Toeplitz matrices, we use them to provide localization results for the eigenvalues of $H_n(f)$. Our study is motivated by the convergence analysis of the minimal residual (MINRES) method for the solution of real non-symmetric Toeplitz linear systems of the form $T_n(f)\mathbf x=\mathbf b$ after pre-multiplication of both sides by $Y_n$, as suggested by Pestana and Wathen.

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