Recently, safe reinforcement learning (RL) with the actor-critic structure for continuous control tasks has received increasing attention. It is still challenging to learn a near-optimal control policy with safety and convergence guarantees. Also, few works have addressed the safe RL algorithm design under time-varying safety constraints. This paper proposes a safe RL algorithm for optimal control of nonlinear systems with time-varying state and control constraints. In the proposed approach, we construct a novel barrier force-based control policy structure to guarantee control safety. A multi-step policy evaluation mechanism is proposed to predict the policy's safety risk under time-varying safety constraints and guide the policy to update safely. Theoretical results on stability and robustness are proven. Also, the convergence of the actor-critic implementation is analyzed. The performance of the proposed algorithm outperforms several state-of-the-art RL algorithms in the simulated Safety Gym environment. Furthermore, the approach is applied to the integrated path following and collision avoidance problem for two real-world intelligent vehicles. A differential-drive vehicle and an Ackermann-drive one are used to verify offline deployment and online learning performance, respectively. Our approach shows an impressive sim-to-real transfer capability and a satisfactory online control performance in the experiment.

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