We consider the estimation of rare-event probabilities using sample proportions output by naive Monte Carlo or collected data. Unlike using variance reduction techniques, this naive estimator does not have a priori relative efficiency guarantee. On the other hand, due to the recent surge of sophisticated rare-event problems arising in safety evaluations of intelligent systems, efficiency-guaranteed variance reduction may face implementation challenges which, coupled with the availability of computation or data collection power, motivate the use of such a naive estimator. In this paper we study the uncertainty quantification, namely the construction, coverage validity and tightness of confidence intervals, for rare-event probabilities using only sample proportions. In addition to the known normality, Wilson's and exact intervals, we investigate and compare them with two new intervals derived from Chernoff's inequality and the Berry-Esseen theorem. Moreover, we generalize our results to the natural situation where sampling stops by reaching a target number of rare-event hits.

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